The second law of thermodynamics does not state that entropy must increase. It states that overall entropy of the whole system increases, but entropy will increase in some places and decrease in others. The second law of thermodynamics is not a certainty but possibilities. There is a greater possibility of entropy increasing then decreasing, therfore overall it increases but in some places it decreases.
For example a box with a pendulum swinging freely without resistance from air or friction. let's say there are 3 particles of gas in box and 11 units of energy in the box. All 11 units of energy comes from the pendulum at the start. If we have 10 units of energy in the pendulum and one in the particles of gas, we have 1 state, being (1,0,0). 1 in the 1st particle 0 in the other 2. if we have 2 units of energy in the particles and 9 in the pendulum, we have 2 possible states. (2,0,0) and (1,1,0). but if we have all 11 units in the particles and none in the pendulum, we will have a total of 16 possible states. The total number of states is calculated to be 83. 1/83 would be 1 unit of energy in particles. 16/83 would be 11 units in particles. THerfore, there is a higher possibility that the final result would be 11 units in the particles and none in the pendulum. BUT it is still possible that the pendulum has more energy at the end. But there is no space with only 3 particles of gas. The more particles the greater the possibility that the particles will have the energy and pendulum none.
Entropy
- whiteholes
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I don't know about entropy, but the above statement seems contradictory in itself.The second law of thermodynamics is not a certainty but possibilities.
Isn't a Law supposed to be -
a. a statement of a relation or sequence of phenomena invariable under the same conditions.
or more importantly -
b. a principle based on the predictable consequences of a condition
thus, I don't see how a law is "not a certainty but possibilities." Then having that in the opening almost negates everything after that ... or maybe I'm not going deep enough ..

*source - Random House Unabridged dictionary
Jeremy Ng
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- whiteholes
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There is this steorotype that entropy can ONLY increase but it is possible for entropy to decrease as illustrated above. Although there is a possibility of it decreasing, the chances of it doing so in our world is very very little.The second law of thermodynamics is not a certainty but possibilities.
The probability of it decreasing is so slight that it never happens. That's why the results can always be predicted.a principle based on the predictable consequences of a condition
Does this clear any doubts? :|
Last edited by whiteholes on Fri Mar 02, 2007 4:35 pm, edited 1 time in total.
Still doesn;t answer the question whether it's a Law or an uncertainty.

Cos from what I gather here, the possibility of it increasing AND decreasing are both very slight ..
In that case, I still don't see the point of discussion here ...
vs.The probability of it decreasing is so slight that it never happens. That's why the results can always be predicted.
seems even more contradictory now ... Are you sure you're using "increasing" and "decreasing" in the right places?Although there is a possibility of it increasing, the chances of it doing so in our world is very very little.

Cos from what I gather here, the possibility of it increasing AND decreasing are both very slight ..
In that case, I still don't see the point of discussion here ...

Jeremy Ng
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- whiteholes
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lol.
understand.
change that to decreasing.Although there is a possibility of it increasing, the chances of it doing so in our world is very very little.
Why doesnt it not answer? It is a law only because you don't observe decreasing entropy. BUT it can decrease. quantum physicsStill doesn;t answer the question whether it's a Law or an uncertainty.



understand.
- wucheeyiun
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